Putin ordered a partial military mobilisation earlier Wednesday and vowed to use "all available means" to protect Russian territory, after Moscow-held regions of Ukraine suddenly announced annexation referendums.
Ukrainian president Volodymyr Zelensky's advisor Mykhaylo Podolyak mocked Moscow's latest steps in a Twitter message.
"Everything is still according to the plan, right? Life has a great sense of humour," he wrote.
"210th day of the 'three-day war'. Russians who demanded the destruction of Ukraine ended up getting: 1. Mobilisation 2. Closed borders, blocking of bank accounts 3. Prison for desertion," said Podolyak.
On Tuesday separatist officials in Moscow-held regions of Ukraine announced urgent votes on annexation by Russia.
Pro-Russia authorities in the eastern Donetsk and Lugansk regions, as well as in the southern Kherson and Zaporizhzhia regions, said they would hold the vote over five days beginning Friday this week.
Washington, Berlin and Paris denounced the ballots and said the international community would never recognise the results while NATO said the votes marked a "further escalation" of the war.
Putin "still refuses to understand Ukraine," said the UK's ambassador in Kyiv.
"Partial mobilisation and sham referenda don't change that essential weakness," Melinda Simmons wrote on Twitter.