The 34-year-old doubled Argentina's lead just before halftime, adding another goal two minutes into the second half. He sealed the score with two more strikes in the 71st and 76th minutes.

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The Argentina captain caught up and left behind the former Hungary and -- on four occasions -- Spain forward, who scored 84 goals in 89 games.

Messi is now three goals behind former Malaysia forward Mokhtar Dahari, in third. Iran's Ali Daei (109) is second, while Portugal's Cristiano Ronaldo remains first with 117 goals.

The Paris St Germain forward also became the first player to have netted five times in both a single European Cup or Champions League clash and in an international match on a senior level.

He previously found the back of the net five times 10 years ago, when Barcelona hammered Bayer Leverkusen 7-1 in the Champions League last 16 second leg at the Camp Nou.

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